Order–disorder and magnetic clusters in some mixed-metal perovskites
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry
- Vol. 3 (6) , 591-596
- https://doi.org/10.1039/jm9930300591
Abstract
The temperature dependence of the 57Fe and 119Sn Mössbauer spectra and the zero-field-cooled and field-cooled magnetic susceptibilities of SrLaFeSnO6, SrEuFeSnO6, BaLaFeSnO6 and CaLaFeSnO6 show the existence of unusual magnetic relaxation behaviour. In the case of CaLaFeSnO6 there is evidence for a non-random distribution of the Fe and Sn, although the other compounds are fully disordered. It is proposed that competition between the first- and second-nearest-neighbour superexchange interactions leads to the formation of magnetic clusters which can grow with decrease in temperature until long-range antiferromagnetic order is achieved.Keywords
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