A general method for the preparation of crystalline iron(III) and gallium(III) catecholamides: X-ray crystal structure of dipiperidinium bis (ethyl 2,3-dihydroxybenzoylglycinato)(pentane-2,4-dionato)-ferrate-tetahydrofuran

Abstract
The synthesis of crystalline or microcrystalline iron(III) and gallium(III) catecholamide chelates of the type X2[M{2,3-(–O)2C6H3CONR1R2}2(acac)](Hacac = pentanedione) and X3M{2,3-(–O)2C6H3CONR1R2}3][X = piperidinium (pip) or tetrabutylammonium cation], and the X-ray crystal structure of [pipH]2[Fe{2,3-(–O)2C6H3CONHCH2CO2Et}2(acac)]–tetrahydrofuran are described.
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