Rotational analysis of the 0 band of the à 3E–X̃ 3A2 system of methylnitrene
- 15 January 1992
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 96 (2) , 919-926
- https://doi.org/10.1063/1.462113
Abstract
The optical emission spectrum of the methylnitrene radical has been observed at a resolution of 0.07 cm−1. Transitions to subbands with K up to 3 in the X̃ 3A2 ground state were observed and a full rotational analysis carried out. Comparison of the structural information with the highest level theoretical calculations shows agreement to within the estimated error.Keywords
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