Structural anomalies in undoped gallium arsenide observed in high-resolution diffraction imaging with monochromatic synchrotron radiation

Abstract
Novel, streaklike disruption features restricted to the plane of diffraction have recently been observed in images obtained by synchrotron radiation diffraction from undoped, semi-insulating gallium arsenide crystals. These features were identified as ensembles of very thin platelets or interfaces lying in {110} planes, and a structural model consisting of antiphase domain boundaries was proposed. We report here the other principal features observed in high resolution monochromatic synchrotron radiation diffraction images: (quasi)cellular structure; linear, very low-angle subgrain boundaries in 〈110〉 directions, and surface stripes in a 〈110〉 direction. In addition, we report systematic differences in the acceptance angle for images involving various diffraction vectors. When these observations are considered together, a unifying picture emerges. The postulate of thin {110} antiphase boundaries leads to an understanding not only of the streak-like diffraction features but of the other principal features as well. For the formation of such regions we propose two mechanisms, operating in parallel, that appear to be consistent with the mesoscopic structure observed by a variety of techniques.