Abstract
AlF3-based fluoride glasses were developed. The glass systems AlF3-YF3-RF2, AlF3-YF3-ZrF4- RF2 (RF2-alkali earth fluoride) have been studied in detail. The relationship between physical properties and chemical composition have been established. The structure of AlF3- based fluoride glasses were studied by Raman and infrared spectroscopy and new structural model has been proposed.

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