Compounds of rhenium(VI)

Abstract
Three rhenium (VI) compounds have been prepared and characterised. The reactions of ReOCl4 with acetonitrile and with anhydrous liquid ammonia give respectively ReOCl4, MeCN, and oxygen-bridged polymeric [ReO(NH2)4]n. The reaction between [PPh4]+Br and ReOBr4 in anhydrous chloroform gives [PPh4]+[ReOBr5].

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