Supramolecular gas–solid reaction between formic acid vapours and solid [CoIII(η5-C5H4COOH)(η5-C5H4COO)]
- 17 September 2002
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 20,p. 2296-2297
- https://doi.org/10.1039/b207581d
Abstract
Exposure of the solid zwitterion [CoIII(η5-C5H4COOH)(η5-C5H4COO)] to vapours of formic acid quantitatively produces the co-crystal [CoIII(η5-C5H4COOH)(η5-C5H4COO)] [HCOOH] without proton transfer from formic acid to the deprotonated –COO− group on the zwitterion; formic acid can be quantitatively removed by mild thermal treatment, regenerating the starting material.Keywords
This publication has 16 references indexed in Scilit:
- Two concomitant polymorphs and two isomorphous forms with different chemical compositions, which transform into the same substance upon thermal treatmentCrystEngComm, 2002
- Reversible Gas−Solid Reactions between the Organometallic Zwitterion [(η5-C5H4COOH)(η5-C5H4COO)CoIII] and Vapors of Trifluoroacetic and Tetrafluoroboric AcidsOrganometallics, 2002
- Seasonality Influence in the Distribution of Formic and Acetic Acids in the Urban Atmosphere of São Paulo City, BrazilJournal of the Brazilian Chemical Society, 2001
- Multivariate evaluation of factors influencing the performance of a formic acid biosensor for use in air monitoringThe Analyst, 2001
- An XPS study of copper corrosion originated by formic acid vapour at 40% and 80% relative humidityMaterials and Corrosion, 2001
- Self-assembled organoplatinum(II) supermolecules as crystalline, SO2 gas-triggered switches †J. Chem. Soc., Dalton Trans., 2000
- Chiral inclusion crystallization of tetra(p-bromophenyl)ethylene by exposure to the vapor of achiral guest molecules: a novel racemic-to-chiral transformation through gas–solid reactionChemical Communications, 2000
- Dynamical processes in crystalline organometallic complexesChemical Reviews, 1992
- Reactions of Organic Crystals with GasesScience, 1975
- Nuclear magnetic resonance spectroscopy. Carbon-13 spectra of aliphatic carboxylic acids and carboxylate anionsJournal of the American Chemical Society, 1969