Pentafluoro-orthotellurates of silicon, germanium, and tin
- 1 January 1973
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 17,p. 600-601
- https://doi.org/10.1039/c39730000600
Abstract
Reaction of Me4Sn, Me3(Si,Ge,Sn)Cl, and SiCl4 with HOTeF5 or AgOTeF5 gives Me3(Si,Ge,Sn)OTeF5 and Si(OTeF5)4; Me3SiOTeF5 has been tested as a reagent for the transfer of the F5TeO group in metathetical reactions with fluorides and the structure of the adducts of Me3SnOTeF5 with MeCN and Me2SO has been studied by i.r. and n.m.r. spectroscopy.Keywords
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