THE POLYMERIC COPPER(II) COMPLEX, 2,2′-BIPYRIDINE-N,N′-(μ-NICOTINATO-O, O′:N) MONOAQUACOPPER (II) NITRATE DIHYDRATE
- 1 November 1996
- journal article
- research article
- Published by Taylor & Francis in Journal of Coordination Chemistry
- Vol. 39 (3-4) , 273-280
- https://doi.org/10.1080/00958979608024335
Abstract
The nicotinate complex of Cu(II), 2,2′-bipyridine(nicotinato)monoaquacopper(II) nitrate dihydrate has been prepared and its crystal structure has been determined by means of X-ray methods. The nicotinate anions bridge adjacent Cu(II) atoms through both the pyridine N atom and the carboxyl group to form infinite chains. The carboxyl group of the nicotinate anion coordinates to the Cu(II) atom as a chelate. Based on the molecular structure the infrared spectrum is discussed.Keywords
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