THE CRYSTAL STRUCTURE OF A NEW CHARGE-TRANSFER SALT OF HEXAMETHYLENETETRATELLURAFULVALENE, (HMTTeF)4(PF6)2

Abstract
The single crystal of (HMTTeF)4(PF6)2 was first prepared by the electrochemical method. The X-ray crystal structure analysis revealed that among four HMTTeF molecules in the unit cell, three are stacked to form trimeric molecular column along the a-axis and the remaining one is located between the HMTTeF columns, having very short intermolecular Te–Te distances with the HMTTeF column.

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