Cobalt-Mediated Synthesis of Propargyl Nitriles and α-Alkoxy Propargyl Nitriles
- 1 January 1989
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 1989 (06) , 454-455
- https://doi.org/10.1055/s-1989-27287
Abstract
Dicobalt hexacarbonyl complexes of propargyl acetates and acetylenic acetals couple efficiently with diethylaluminum cyanide to produce the corresponding complexed propargyl nitriles and cyanohydrin derivatives, respectively. A convenient procedure far preparing propargyl nitriles and α-alkoxy propargyl nitriles from propargyl alcohols and acetylenic acetals using this methodology is described.Keywords
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