Synthesis, Characterization and Thermal Reactivity of Mixed Metal Hydrazidocarboxylate Hydrazinates
- 1 January 1995
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 25 (1) , 127-138
- https://doi.org/10.1080/15533179508218208
Abstract
Metal hydrazidocarboxylate hydrazinates, M1/3Co2/3(N2H3COO)2(N2H4)2, where M = Mn, Fe, Co, Ni, Zn and Cd, have been prepared and characterized by chemical analyses and infrared spectra. The thermoanalytical properties of these complexes have been investigated using TG and DTA. The complexes decompose in air below 300°C to yield metal cobaltites, MCo2O4. The decomposition behaviour was autocatalytic. Formation of cobaltites has been confirmed by thermogravimetry weight loss, infrared spectroscopy and X-ray diffraction.Keywords
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