The reactions of some silylamines with carbon dioxide and related molecules
- 1 January 1967
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 362-365
- https://doi.org/10.1039/j19670000362
Abstract
Trisilylamine and N-methyldisilylamine do not react with carbon dioxide, carbon disulphide, or carbon oxysulphide at up to 100° and pressures up to 30 atmospheres. NN-Dimethylsilylamine combines with carbon dioxide to give silyl NN-dimethylcarbamate, and with carbon disulphide to give silyl NN-dimethyldithiocarbamate; with carbon oxysulphide, a compound is produced, formulated as O-silyl NN-dimethylmonothiocarbamate, whose n.m.r. spectrum indicates that rotation about the Me2N–C bond is restricted.Keywords
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