An η2-allene complex of rhenium formed form an alkyne: X-ray structure of [ReCl(η2-H2C–CCHPh)(Ph2PCH2CH2PPh2)2]
- 1 January 1984
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 992-993
- https://doi.org/10.1039/c39840000992
Abstract
Treatment of trans-[ReCl(N2)(dppe)2](dppe = Ph2PCH2CH2PPh2) with PhCCCH3 in refluxing benzene or tetrahydrofuran gives a product shown by X-ray analysis to be the η2-phenylallene complex [[graphic omitted]CHPh)(dppe)2].Keywords
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