AROMATIC PHOSPHONATE-PHOSPHINES
- 1 October 1996
- journal article
- research article
- Published by Taylor & Francis in Phosphorus, Sulfur, and Silicon and the Related Elements
- Vol. 117 (1) , 287-292
- https://doi.org/10.1080/10426509608038791
Abstract
Aromatic phosphonate-phosphines 3a,b are obtained by reaction of 4-halogen-substituted phenylphosphonates 2a,b,c and lithium diphenylphosphide. They can be transformed into air-stable phosphine-horanes 4a,b by co-ordination of the borane-THF complex. The reaction of the phosphonate-phosphine 3b with |ClRh(cod)|2 affords the corresponding rhodium phosphine complex 5. The cyclic phosphinate 8 with a hinaphthalene skeleton can be obtained by a new cyclisation reaction of 2-promo-2′-diisopropylphosphono-hinaphthalene 7 with lithium diphenylphosphide.Keywords
This publication has 13 references indexed in Scilit:
- Recent advances in enantioselective hydroformylationTetrahedron: Asymmetry, 1995
- PHOSPHONSÄUREESTER-PHOSPHANE ALS HEMILABILE KOMPLEXLIGANDENPhosphorus, Sulfur, and Silicon and the Related Elements, 1995
- Cis-[RhI(CO)(Ph2PCH2P(S)Ph2)]: a new catalyst for methanol carbonylationJournal of the Chemical Society, Chemical Communications, 1995
- Phosphine vs. phosphine oxide ligands in hydroformylation reactionsJournal of the Chemical Society, Chemical Communications, 1994
- Influence of (PN) bidentate ligand on rhodium-catalyzed hydroformylation of olefinsJournal of Molecular Catalysis, 1993
- Metallkomplexkatalysatoren mit Phosphonsäureester-Phosphan-Liganden. I. Carbonylierung von Methanol mit Phosphonsäureester-Phosphan-Rhodiumkomplexen in der FlüssigphaseAdvanced Synthesis & Catalysis, 1993
- Synthesis and reactions of phosphine-boranes. Synthesis of new bidentate ligands with homochiral phosphine centers via optically pure phosphine-boranesJournal of the American Chemical Society, 1990
- Neuartige basische Liganden für die homogenkatalytische Methanolcarbonylierung, XVI. (Ether‐Phosphan)‐Rhodium‐Komplexe als Modellverbindungen in der MethanolcarbonylierungEuropean Journal of Inorganic Chemistry, 1988
- Palladium-catalyzed New Carbon-Phosphorus Bond FormationBulletin of the Chemical Society of Japan, 1982
- Reaktion von Arylhalogeniden mit Trialkylphosphiten und Benzolphosphonigsäure‐dialkylestern zu aromatischen Phosphonsäureestern und Phosphinsäureestern unter NickelsalzkatalyseEuropean Journal of Inorganic Chemistry, 1970