Modified Cyclodextrins—Novel, Highly Enantioselective Stationary Phases for Gas Chromatography
- 1 July 1988
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 27 (7) , 979-980
- https://doi.org/10.1002/anie.198809791
Abstract
Enantiomer separation by gas chromatography in a few minutes and at temperatures between 45 and 130°C is now possible for compounds which cannot form H‐bonds. For peralkylated or partially alkylated and acylated cyclodextrins separation factors of between 1.021 and 1.279 have been achieved. The enantioselectivity of the stationary phase depends—at least partially—on inclusion effects.Keywords
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