Preparation, crystal structure, and magnetic properties of a trinuclear mixed-valence manganese carboxylate
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 62-63
- https://doi.org/10.1039/c39780000062
Abstract
The reaction of [Mn(H2O)2(O2CMe)3] with pyridine (py) produces the antiferromagnetic trinuclear complex [Mn3(py)3O(O2CMe)6], whose molecular structure, determined by X-ray methods, shows all three manganese atoms to be equivalent, with an average oxidation state of 2⅔.Keywords
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