Synthesis of cationic pentacarbonyl, fac- and mer-tricarbonyl, and cis-and trans-dicarbonyl complexes of manganese(I)
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 6,p. 996-1002
- https://doi.org/10.1039/dt9790000996
Abstract
The complexes [Mn(CO)5(OClO3)] and fac-[Mn(CO)3(OCMe2)3][ClO4] obtained by the reaction of [Mn(CO)5Br] with Ag[ClO4] in dichloromethane or acetone solution are suitable precursors for the synthesis of cationic complexes of the type [Mn(CO)5L][ClO4] and of the types fac-[Mn(CO)3L3][ClO4] and cis-[Mn(CO)2L4][ClO4](L = a Group 5B ligand) which, when L is a strong π acceptor, isomerize under reflux to mer-[Mn(CO)3L3][ClO4] or, respectively, to trans-[Mn(CO)2L4][ClO4].Keywords
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