Diastereoselective Michael Addition of Organolithium Reagents to Chiral α,β-Unsaturated Selenoamide

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Abstract
The addition of organolithium reagents to chiral α,β-unsaturated selenoamide 1 selectively took place at the β-carbon atom to the selenocarbonyl group with high stereoselectivity. The stereochemistry of the product was determined by converting the product 4 into γ-butyrolactone 6.

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