Comments on the competitive preferential solvation theory
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Faraday Transactions
- Vol. 86 (2) , 307-309
- https://doi.org/10.1039/ft9908600307
Abstract
Simple additive relationships for the physico-chemical properties of a solute dissolved in binary solvent mixtures are developed from the competitive preferential solvation model. Additive expressions for solute mole fraction solubility and logarithm of solute solubility are mathematically identical to equations derived previously from the microscopic partition and basic nearly ideal binary solvent models. Calculated values based on the various additive relationships are compared to carbazole solubilities in ten binary solvent mixtures containing dibutyl ether with n-hexane, n-heptane, n-octane, cyclohexane, cyclo-octane, methylcyclohexane, iso-octane, n-hexadecane, squalane and t-butylcyclohexane.Keywords
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