Direct Electrochemical Synthesis of Anionic Complexes of Metallic Elements
- 1 January 1976
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 6 (2) , 105-113
- https://doi.org/10.1080/00945717608057347
Abstract
The tetraethylammonium salts of the anionic bromo complexes of Fe(III), Co(II), Ni(II), Cu(II), Au(III), Cd(II), In(III) and Sn(IV) have been prepared in gram quantities by the direct electrochemical oxidation of the metal in question. The novel features of the method are (a) its simplicity and speed; (b) the solution phase, which consists of (C2H5)4NBr + Br2 in 80:20 benzene: methanol; and (c) the high applied voltage (∼ 50 v).Keywords
This publication has 2 references indexed in Scilit:
- Direct electrochemical synthesis of indium compoundsJournal of the Chemical Society, Chemical Communications, 1975
- The electronic properties and stereochemistry of mono-nuclear complexes of the copper(II) ionCoordination Chemistry Reviews, 1970