Crystal chemistry of inorganic compounds based on chains of oxocentered tetrahedra
- 1 December 1998
- journal article
- Published by Walter de Gruyter GmbH in Zeitschrift für Kristallographie - Crystalline Materials
- Vol. 213 (12) , 645-649
- https://doi.org/10.1524/zkri.1998.213.12.645
Abstract
The crystal structure of chloromenite, Cu9O2(SeO3)4Cl6, a = 14.170(3) Å, b = 6.262(1) Å, c = 12.999(3) Å, β = 113.05(1)°, V = 1061.3(4) Å3, Z = 2, space group I2/m, has been solved by direct methods and refined to an R(F) index of 0.051 (wR(F 2) = 0.128). The structure is based on unbranched zweier single chains {uB, 11 ∞} [O2Cu6] of corner sharing [OCu4] tetrahedra running parallel to the b axis. The geometry of structurally similar [uB, l1 ∞}[O2M6] (M = Cu, Zn) chains of oxocentered [OM4] tetrahedra (M = Cu, Zn) in inorganic compounds is discussed.Keywords
This publication has 9 references indexed in Scilit:
- Crystal chemistry of inorganic compounds based on chains of oxocentered tetrahedraZeitschrift für Kristallographie - Crystalline Materials, 1998
- Zum System Zn/Mo/O. I. Phasenbestand und Eigenschaften der ternären Zinkmolybdate; Struktur von Zn3Mo2O9Zeitschrift für anorganische und allgemeine Chemie, 1996
- A Novel Copper(I/II) Oxophosphate Chloride with a Quasi-One-Dimensional μ4-Oxo-Bridged Copper(II) Chain. Crystal Structure and Magnetic Properties of [Na2CuII3(PO4)2][CuIOCl]Inorganic Chemistry, 1996
- A Decanuclear Manganese Cluster with Oxo and Halide Bridging Ligands: Magnetic Behavior of an S .gtoreq. 12 SystemJournal of the American Chemical Society, 1995
- Structure and magnetism of novel tetranuclear µ4-oxo-bridged copper(II) complexesJ. Chem. Soc., Dalton Trans., 1995
- The influence of cation properties on the shape of silicate chainsZeitschrift für Kristallographie - Crystalline Materials, 1981
- Die Kristallstruktur von einem Sulfat-reichen Oxidsulfat des ZinksThe Science of Nature, 1981
- The symmetry of Cu3Mo2O9Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1972
- The crystal structure of Cu3Mo2O9Acta Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1971