Binding of Similarly Charged Plates with Counterions Only
Top Cited Papers
- 26 July 2001
- journal article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 87 (7) , 078301
- https://doi.org/10.1103/physrevlett.87.078301
Abstract
Similarly and highly charged plates in the presence of multivalent counterions attract each other and form electrostatically bound states. Using Monte-Carlo simulations, we obtain the interplate pressure in the global parameter space. The equilibrium plate separation, where the pressure changes from attractive to repulsive, exhibits a novel unbinding transition. A systematic and asymptotically exact strong-coupling field theory yields the bound state from a competition between counterion entropy and electrostatic attraction, in agreement with simple scaling arguments and simulations.Keywords
This publication has 18 references indexed in Scilit:
- Charge fluctuations and membrane attractionsEurophysics Letters, 1998
- Charge reversal seen in electrical double layer interaction of surfaces immersed in 2:1 calcium electrolyteThe Journal of Chemical Physics, 1993
- Ionic surfactants with divalent counterionsAdvances in Colloid and Interface Science, 1991
- Density Functional Theory of Ionic Screening: When Do Like Charges Attract?Europhysics Letters, 1990
- An analytic treatment of the first-order correction to the Poisson-Boltzmann interaction free energy in the case of counterion-only Coulomb fluidJournal of Physics A: General Physics, 1990
- Attractive double-layer interactions between calcium clay particlesJournal of Colloid and Interface Science, 1988
- Beyond Poisson–Boltzmann: Images and correlations in the electric double layer. I. Counterions onlyThe Journal of Chemical Physics, 1988
- Double-layer interaction in the primitive model and the corresponding Poisson-Boltzmann descriptionThe Journal of Physical Chemistry, 1986
- Correlation and image charge effects in electric double layersChemical Physics Letters, 1984
- Electrical double layer forces. A Monte Carlo studyThe Journal of Chemical Physics, 1984