Novel synthesis of benzotrihalides: the pyrolysis of phenyl trihalogenoacetates
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 714a
- https://doi.org/10.1039/c3978000714a
Abstract
Pyrolysis of 4-chlorophenyl trichloroacetate (I) at 500 °C yields 4-chlorobenzotrichloride (II) and some 1,4-dichlorobenzene (III) as by-product; the corresponding trifluoroacetate is converted into 4-chlorobenzotrifluoride.Keywords
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