On the existence of peroxocarbonates in aqueous solution
- 1 January 1986
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 20-21
- https://doi.org/10.1039/c39860000020
Abstract
The presence of a peroxocarbonate species, likely to be HCO4 – in pH-dependent equilibrium with CO4 2–, in solutions of HCO3 – in an excess of H2O2 is inferred from Raman and 13C n.m.r. spectroscopy; similar evidence is presented for the presence of CO4 2– in solutions prepared by dissolving solid peroxocarbonates (NaHCO4·H2O and K2C2O6) in aqueous alkali.Keywords
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