Reduction of semiclassical phase shifts for potential scattering to resonance form
- 1 April 1972
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 23 (4) , 717-735
- https://doi.org/10.1080/00268977200100721
Abstract
The semiclassical theory of shape or orbiting resonances is discussed within the context of the Jost function approach to potential scattering. The S matrix is considered as a function of four variables : energy, angular momentum, potential coupling constant and mass, each of which is allowed to take complex values. A semiclassical quantization condition is obtained which determines the poles of the S matrix. For a sharp resonance, the S matrix reduces to a Breit-Wigner form and it is shown that the use of these four variables provides an equivalent description of a resonance in this case. In addition the semiclassical analysis of the three-turning-point problem is extended to that of five turning points. The five-turning point case occurs in the elastic scattering of reactive systems and in the scattering of excited states of diatomic systems.Keywords
This publication has 40 references indexed in Scilit:
- Calculation of the Width of Narrow Shape ResonancesThe Journal of Chemical Physics, 1971
- Resonances in reactive collisions: Computational study of the H + H2 collisionChemical Physics Letters, 1971
- On the Relation between Unimolecular Reaction and PredissociationThe Journal of Chemical Physics, 1971
- Shape Resonances and Rotationally Predissociating Levels: The Atomic Collision Time-Delay Functions and Quasibound Level Properties of H2(X 1Σg+)The Journal of Chemical Physics, 1971
- Quasi-bound states in molecular collisionsAccounts of Chemical Research, 1970
- An approximate treatment of shape resonances in elastic scatteringMolecular Physics, 1970
- On the semi-classical description of molecular orbiting collisionsMolecular Physics, 1968
- Numerical Evaluation of Barrier Penetration and Resonance Effects on Phase ShiftsThe Journal of Chemical Physics, 1966
- Resonance scattering theoryPhysics Letters, 1963
- Analyticity in Coupling Constant, Angular Momentum and Energy of the S -Matrix for Potential ScatteringProgress of Theoretical Physics, 1963