Use of the 2,5-bis-(tert-butyl)phospholide anion as an η5-ligand: stabilisation of η5-phospholyl complexes of ruthenium and rhodium
- 1 January 1994
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 10,p. 1167-1168
- https://doi.org/10.1039/c39940001167
Abstract
The 2,5-bis-(tert-butyl)phospholide anion promotes η5-complexation to late transition metals in cases where unhindered phospholyls may favour η1-ligation through the phosphorus lone pair.Keywords
This publication has 8 references indexed in Scilit:
- Syntheses and 31P NMR studies of ruthenium(II), rhodium(I), and rhodium(III) complexes containing η5-P2C3tBu3 and η5- and η1-P3C2tBu2 ligated ring systems. Crystal structures of [Rh(η5-P2C3tBu3)(η4-COD)] (COD = 1,5-cyclooctadiene) and the novel hydrido-η1-triphosphacyclopentadienyl complex [RhH(η1-P3C2tBu2)(η5C5Me5)PPh3]Journal of Organometallic Chemistry, 1993
- XVI. (2,5-C4tBu2RHN)MCl3 (M Ti, Zr, Hf; R H, SiMe3)—Azacyclopentadienyl-Komplexe der Gruppe 4-MetalleJournal of Organometallic Chemistry, 1992
- Theoretical study of conformations of some heterocyclic transition-metal complexesThe Journal of Physical Chemistry, 1989
- Coordination chemistry of compounds containing phosphorus-carbon multiple bondsChemical Reviews, 1988
- PentaphosphametalloceneEuropean Journal of Inorganic Chemistry, 1988
- Chemistry of 3,4-dimethylphospholyl anion in the coordination sphere of tungsten: synthesis and x-ray crystal structure analysis of (η5,3-4-dimethylphospholyl)tricarbonyl-iodotungstenPolyhedron, 1986
- Preparation of 3,3',4,4'-tetramethyl-1,1'-biphospholyl and its reactions with iron and cobalt carbonyls. Synthesis and x-ray crystal structure of a phospholyl complex with a chain of four cobalt atomsOrganometallics, 1983
- Barriers to pyramidal inversion at phosphorus in phospholes, phosphindoles, and dibenzophospholesJournal of the American Chemical Society, 1971