Analytic electron-ion effective potentials for
- 1 March 1981
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review A
- Vol. 23 (3) , 1008-1014
- https://doi.org/10.1103/physreva.23.1008
Abstract
Analytic -dependent electron-ion potentials have been obtained for all isoelectronic sequences from He to Cs. These potentials have a parametrized Yukawa component for each electron shell. Parameter values were determined by iteratively solving the Dirac equation until a match with experimental ionization energies was obtained. The screening parameters for each isoelectronic sequence were fit to simple -dependent functions. Working systematically through the periodic table and using preceding fits to obtain the screening parameters for closed inner shells, I found it necessary to evaluate only the screening parameter for the valence shell of the parent ion. Excited states having the same parentage as the ground state are also given to good accuracy by these potentials. The energy offset of excited states having a different parentage than the ground state is obtained from simple -dependent functions.
Keywords
This publication has 22 references indexed in Scilit:
- Independent-particle-model potentials for atoms and ions withand a modified Thomas-Fermi atomic energy formulaPhysical Review A, 1975
- Independent-particle-model potentials for ions and neutral atoms withPhysical Review A, 1974
- Relativistic Independent-Particle Model for Atoms, Based on Analytical PotentialsPhysical Review A, 1971
- Potential-Scattering Model for Electrons on Helium and Other AtomsPhysical Review A, 1970
- Statistical Electron-Density Distributions and Thomas-Fermi-Dirac Screening Functions for Positive Ions with Degree of Ionization One through FourPhysical Review B, 1969
- Analytic Independent-Particle Model for AtomsPhysical Review B, 1969
- Binding Energies of Electrons in Positive Ions for Statistical PotentialsPhysical Review B, 1967
- Statistical Electron Density Distributions and Thomas-Fermi-Dirac Screening Functions for Neutral AtomsPhysical Review B, 1961
- Atomic Energy Levels for the Thomas-Fermi and Thomas-Fermi-Dirac PotentialPhysical Review B, 1955
- Die Statistische Theorie des Atoms und ihre AnwendungenPublished by Springer Nature ,1949