Pressure- and field-dependent behavior ofAu
- 1 October 1994
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 50 (13) , 9300-9307
- https://doi.org/10.1103/physrevb.50.9300
Abstract
Temperature- and pressure-dependent measurements of the electrical resistivity ρ(T,p) of the ternary compound Au have been performed. These investigations yield an increase of the antiferromagnetic transition temperature from 0.6 K at ambient pressure up to more than 2 K at 50 kbar. The bulk modulus has been determined (≊1.4 Mbar) at room temperature which together with ∂/∂p≊0.044 K/kbar derived from ρ(T,p) allows an estimation of the Grüneisen constant Ω()≊60. A study of the field-dependent behavior of the specific heat justifies an antiferromagnetic ground state. In the scope of an empirical model, the Kondo temperature of Au was obtained to be 1.65 K, which is significantly smaller than the energy of the first excited crystal-field level above the ground-state doublet.
Keywords
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