Semiclassical Perturbation Theory of Molecular Collisions. I. First and Second Order
- 1 September 1970
- journal article
- conference paper
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 53 (5) , 1815-1831
- https://doi.org/10.1063/1.1674259
Abstract
Explicit formulas are derived for the first- and second-order semiclassical rotationally inelastic transition probability with an electric multipole potential. The symmetry properties of the second-order integrals are discussed, and a method for their evaluation is presented. An expression for the interference terms between first- and second-order perturbation theory is also derived.Keywords
This publication has 20 references indexed in Scilit:
- Semiclassical Perturbation Theory of Molecular Collisions. II. The Calculation of Collision Cross SectionsThe Journal of Chemical Physics, 1970
- Vibrational and Rotational RelaxationAnnual Review of Physical Chemistry, 1968
- Scattering Theory of Pressure Broadening of Rotational and Vibration–Rotation TransitionsThe Journal of Chemical Physics, 1968
- Classical Theory of Rotational Relaxation of Diatomic MoleculesThe Journal of Chemical Physics, 1967
- CALCULATION OF THE PRESSURE BROADENING OF ROTATIONAL RAMAN LINES DUE TO MULTIPOLAR AND DISPERSION INTERACTIONCanadian Journal of Physics, 1966
- Impact Broadening of Microwave SpectraPhysical Review B, 1966
- The first Born approximation for collisions between heavy particlesProceedings of the Physical Society, 1966
- On the equivalence of the wave and impact parameter treatments of high-energy heavy particle collisionsProceedings of the Physical Society, 1966
- Bipolar Expansion of Coulombic PotentialsPhysical Review B, 1951
- On the Mathematical Equivalence of two ways of regarding the Excitation of an Atom by a Fast Moving α-particleMathematical Proceedings of the Cambridge Philosophical Society, 1931