The X-ray crystal structure of vanadium oxide trifluoride and its relationship to those of vanadium tetrafluoride and chromium dioxide difluoride
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 22,p. 1474b-1475
- https://doi.org/10.1039/c2970001474b
Abstract
Vanadium oxide trifluoride has unit cell dimensions very similar to those of vanadium tetrafluoride and chromium dioxide difluoride: in the solid, vanadium atoms are linked into pairs through di-µ-fluorobridges, and these units are linked into sheets by cis-bridging fluorine atoms, giving a distorted octahedral arrangement around each vanadium atom.Keywords
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