Tuning of ZnSe–GaAs band discontinuities in heterojunction diodes

Abstract
The conduction band offset in ZnSe/GaAs np heterodiodes was determined from measurements of the low‐temperature tunneling current of photoinjected carriers. We found widely different discontinuities for heterojunctions fabricated with different Zn/Se flux ratios, with conduction band offsets as high as 0.75 eV for Se‐rich interfaces, and as low as 0.26 eV for Zn‐rich interfaces.

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