The Formation of the Rhodium Carbonyl Complexes from Chlorotris-[triphenylphosphine]rhodium with Alcohols in the Presence of Diene and Olefin
- 1 January 1975
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 48 (1) , 353-354
- https://doi.org/10.1246/bcsj.48.353
Abstract
The decarbonylation of alcohols using chlorotris[triphenylphosphine]rhodium in the presence of diene or olefin occurs with the formation of the rhodium carbonyl complex and a hydrocarbon originating from the alcohol. The most suitable reaction system is rhodium compound/methanol/butadiene. The results suggest catalysis by a rhodium species.Keywords
This publication has 2 references indexed in Scilit:
- Organic syntheses by means of noble metal compounds. XXXIV. Carbonylation and decarbonylation reactions catalyzed by palladiumJournal of the American Chemical Society, 1968
- Decarbonylation of aromatic carbonyl compounds catalyzed by rhodium complexesJournal of the American Chemical Society, 1967