THREE NEW DAPHNIPHYLLUM ALKALOIDS WITH AN αβ,γδ-UNSATURATED ESTER GROUP FROM DAPHNIPHYLLUM GRACILE GAGE

Abstract
Three new alkaloids have been isolated from the bark of Daphniphyilum gracile Gage, and their structures with an αβ,γδ-unsaturated ester group also been elucidated on the basis of their spectral and chemical properties. In addition, it is chemotaxonomically important that daphniphylline, one of the main alkaloids found in the Japanese species, has also been detected in this experiment, while this alkaloid has not been found in the leaves of the same plant.

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