The X-ray structure of phomopsin A, a hexapeptide mycotoxin
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 15,p. 1219-1221
- https://doi.org/10.1039/c39860001219
Abstract
A crystallographic study of phompsin A, the hexapeptide mycotoxin of Phomopsis leptostromiformis responsible for lupinosis disease in animals, has shown that it is a linear peptide, modified by an ether bridge in place of the hydroxy groups of the N-methyl-3-(3-chloro-4,5-dihydroxyphenyl)-3-hydroxyalanine and 3-hydroxyisoleucine units, and thus containing a 13-membered ring.Keywords
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