Selective ethane ammoxidation to acetonitrile on alumina-supported niobium–antimony oxides
- 1 January 1991
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 16,p. 1081-1083
- https://doi.org/10.1039/c39910001081
Abstract
Acetonitrile can be synthesized from ethane by heterogeneous catalytic ammoxidation using Nb–Sb mixed oxides supported on alumina; a new type of (amm)oxidation active site on the catalyst, which can lead to a selective insertion of O–N atoms on the double bond of the intermediate ethylene is suggested.Keywords
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