Model reactions for nitrogen fixation. Photo-induced formation and X-ray crystal structure of [Os2(NH3)8(MeCN)2(N2)]5+ from [Os VI (NH3)4N]3+
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1883-1884
- https://doi.org/10.1039/c39890001883
Abstract
UV-VIS irradiation of an acetonitrile solution of [OsVI(NH3)4N](CF3SO3)3 and organic donors under degassed conditions gave [Os2(NH3)8(MeCN)2(N2)]5+; the X-ray crystal structure of the µ-dinitrogen complex has been determined and the Os–N(N2) distances found to be 1.873(9) and 1.893(9)Å.Keywords
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