A General Approach to the Pseudopterosins and Their C-11 and C-13 Stereoisomers. Construction of the Tricyclic Skeleton of the Pseudopterosins
- 1 January 1991
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1991 (07) , 465-468
- https://doi.org/10.1055/s-1991-20762
Abstract
An enantioselective approach to analogues of the pseudopterosin family of structures, which entails the Diels-Alder reaction of a ß-nitroacrylate derivative (dimethyl (E)-3-nitro-2-pentenedioate) with an (S)-carvone-derived silyloxydiene [(3S,6S)-3 - (1,2- isopropylidenedioxy-1-methylethyl) - 6 - methyl -1- (1- trimethylsilyloxyethenyl)-1-cyclohexene], is described.Keywords
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