Iron(II) catalysis in substitution reactions of amminepentacyano- and aquopentacyano-ferrate(III) ions
- 1 January 1974
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 12,p. 1273-1278
- https://doi.org/10.1039/dt9740001273
Abstract
Substitution reactions of the ions [FeIII(CN)5X]2–(X = NH3 and H2O) by Y {Y = N3 –, SCN–, OH–, and [Co(CN)6]3–} are catalysed by [FeII(CN)5X]3–. At iron(II) concentrations greater than ca. 1% of the total iron species present, the rate-determining step of these reactions is substitution of the ions [FeII(CN)5X]3– by Y.Keywords
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