Nucleophilicity of zerovalent platinum acetylene complexes
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 4,p. 199-200
- https://doi.org/10.1039/c29710000199
Abstract
Tetrachloro-o-benzoquinone undergoes a novel oxidative-elimination reaction with Pt(PhCCPh)(PPh3)2 to give the platinum(II) diphenylacetylene complex, Pt-(O2C6Cl4)(PhCCPh)(PPh3): mercuric halides add to Pt(CF3CCCF3)(PMePh2)2 to give vinyl complexes, cis-PtCl[CF3CC(HgCl)CF3](PMePh2)2, with retention of configuration about the double bond and platinum.Keywords
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