Electrochemical and IR/UV−Vis Spectroelectrochemical Studies of fac-[Mn(X)(CO)3(iPr-DAB)]n (n = 0, X = Br, Me, Bz; n = +1, X = THF, MeCN, nPrCN, P(OMe)3; iPr-DAB = 1,4-Diisopropyl-1,4-diaza-1,3-butadiene) at Variable Temperatures: Relation between Electrochemical and Photochemical Generation of [Mn(CO)3(α-diimine)]-
- 1 October 1997
- journal article
- research article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 16 (21) , 4675-4685
- https://doi.org/10.1021/om9702791
Abstract
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This publication has 40 references indexed in Scilit:
- Real-time Fourier transform IR (FTIR) spectroscopy in organometallic chemistry: mechanistic aspects of the fac to mer photoisomerization of fac-[Mn(Br)(CO)3(R-DAB)]Journal of Photochemistry and Photobiology A: Chemistry, 1997
- X-ray Structure of fac-IMn(CO)3(bpy) and Electronic Structures and Transitions of the Complexes fac-XMn(CO)3(bpy) (X = Cl, I) and mer-ClMn(CO)3(bpy)Inorganic Chemistry, 1995
- Rate and Mechanism of the Reductions of Iron Pentacarbonyl and Chromium Hexacarbonyl to Their Metalate ComplexesOrganometallics, 1995
- Role of an electron‐transfer chain reaction in the unusual photochemical formation of five‐coordinated anions [Mn(CO)3(α‐diimine)]− from fac‐[Mn(X)(CO)3(α‐diimine)] (X = halide) at low temperaturesRecueil des Travaux Chimiques des Pays-Bas, 1995
- Metal to Ligand Charge-Transfer Photochemistry of Metal-Metal-Bonded Complexes. 12. The Primary Photoprocess of (CO)5ReMn(CO)3(.alpha.-diimine) Complexes Studied by Temperature- and Pressure-Dependent Photochemistry and Pico- and Nanosecond Flash PhotolysisInorganic Chemistry, 1994
- Radical intermediates in the reductive isomerisation of octahedral manganese carbonyl bipyridyl complexes; electrochemistry, electron spin resonance spectroscopy and molecular-orbital calculationsJ. Chem. Soc., Dalton Trans., 1994
- Metal to ligand charge-transfer photochemistry of metal-metal-bonded complexes. 10. Photochemical and electrochemical study of the electron-transfer reactions of Mn(CO)3(.alpha.-diimine)(L) (L = N-, P-donor) radicals formed by irradiation of (CO)5MnMn(CO)3(.alpha.-diimine) complexes in the presence of LOrganometallics, 1991
- Dynamic IR spectroscopy: occurrence and predictability of coalescence in the carbon monoxide stretching vibrations of 13CO-enriched tricarbonyl(.eta.4-norbornadiene)ironJournal of the American Chemical Society, 1991
- Metal to ligand charge-transfer photochemistry of metal-metal-bonded complexes. 8. Photochemistry of (pentacarbonylmanganese)tricarbonyl(.alpha.-diimine)manganese complexes. Coupling reactions of the radicals formed and x-ray structure of the photoproduct (CO)4Mn(.sigma.-N,.sigma.-N',.eta.2-CN-iso-Pr-PyCa)Mn(CO)3 (iso-Pr-PyCa = pyridine-2-carbaldehyde-N-isopropylimine).Inorganic Chemistry, 1991
- Vibrational Spectra and Bonding in Metal Carbonyls. I. Infrared Spectra of Phosphine-substituted Group VI Carbonyls in the CO Stretching RegionJournal of the American Chemical Society, 1962