Reductive Elimination of [Ph2CCCHPR3]BF4 from the Rhodium(III)−Allenyl Derivatives [Rh(acac){CHCCPh2}(PR3)2]BF4 (PR3 = PCy3, PiPr3)
- 1 October 1997
- journal article
- research article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 16 (21) , 4572-4580
- https://doi.org/10.1021/om970567x
Abstract
No abstract availableThis publication has 36 references indexed in Scilit:
- Substitution and Oxidative Addition Reactions of the Monoolefin Complex Rh(acac)(cyclooctene)(PCy3) Including the X-ray Structure Analyses of Rh(acac)(PCy3)2 and [Rh(acac){(E)-CHCHCy}(PCy3)2]BF4Organometallics, 1996
- New Organophosphorus Ligands: Cyclopropanation and Other Reactions of Cumulenes Bearing Diphenylphosphanyl SubstituentsEuropean Journal of Inorganic Chemistry, 1995
- Synthesis of trans-(.sigma.-allenyl)platinum(II) and -palladium(II) compounds. X-ray crystal structure of trans-[PtBr{C(H):C:CMe2}(PPh3)2] and highly diastereoselective trans-cis isomerization of (.sigma.-allenyl)palladium(II) bromidesOrganometallics, 1994
- Vinylidene transition-metal complexes. 24. Reactions of diynes with [RhCl(PiPr3)2]: unsaturated C4 and partly unsaturated C6 chains between two rhodium centersOrganometallics, 1993
- Synthesis, structure, and reactivity of allene complexes of the chiral rhenium fragment [(.eta.5-C5H5)Re(NO)(PPh3)]+Organometallics, 1992
- The development of versions 3 and 4 of the Cambridge Structural Database SystemJournal of Chemical Information and Computer Sciences, 1991
- Preparation and chemical reactivities of the tungsten allenyl complex CpW(CO)3CH:C:CH2Organometallics, 1990
- Synthese und Struktur einfacher Mono‐ und Bis(phosphino)alleneEuropean Journal of Inorganic Chemistry, 1987
- Transition-metal-cyanocarbon chemistry. 2. Cyanoacetylenes insertions into the metal-hydrogen bond of (.eta.5-C5H5)(CO)3MH (M = Mo, W) complexes. Formation of phosphorus ylide complexes and the structure of (.eta.5-C5H5)(CO)2Mo[.eta.2-C(CN)PPh3CHCN]Organometallics, 1983
- X-Ray molecular structure of dicarbonyl-η5-cyclopentadienyl-(η2-tetramethylallenyl)iron tetrafluoroborate. A sterically crowded allene complexJournal of the Chemical Society, Chemical Communications, 1975