Fourier transform intracavity laser absorption spectra of the 6ν1 band of CHD3
- 15 January 1992
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 96 (2) , 972-975
- https://doi.org/10.1063/1.462117
Abstract
Absorption spectra in the 16 100-16 320 cm-1 region have been recorded for gaseous CHD3 at room temperature with 0.12 cm -1 resolution using a Fourier transform intracavity laser absorption technique. Two bands belonging to the N = 6 polyad, 61 (6ν1) and 62 (5ν1 + 2ν5), were identified and a rotational analysis for 61 including transitions up to J = 13, verified by means of ground-state combination differences, is reported. Comparison with rotational contants obtained from photoacoustic laser spectra at 77 K is discussed. © 1992 American Institute of Physics.Research Project Nos. PB89-0041 and PB87-0273 of the Comision Interministerial de Ciencia y Tecnologia (CICYT).Peer RevieweKeywords
This publication has 11 references indexed in Scilit:
- FT intracavity laser spectroscopy: The B-X transition of Cl2Journal of Molecular Spectroscopy, 1991
- Spectra and Dynamics of Coupled Vibrations in Polyatomic MoleculesAnnual Review of Physical Chemistry, 1990
- Rotationally resolved overtone transitions of CHD3 in the visible rangeThe Journal of Chemical Physics, 1989
- Vibrational spectrum and potential energy surface of the CH chromophore in CHD3The Journal of Chemical Physics, 1988
- Rotational structure of overtone transitions of CHD3 near 13 500 cm−1The Journal of Chemical Physics, 1987
- High-energy overtone spectroscopy of some deuterated methanesThe Journal of Chemical Physics, 1985
- The high-resolution visible overtone spectrum of CH4 and CD3H at 77 KThe Journal of Chemical Physics, 1984
- A new approach for vibronic ground-state analysis of C3v molecules: Application to 12CD3HJournal of Molecular Spectroscopy, 1982
- Quantitative measurements of very weak H2O absorption lines by time resolved intracavity laser spectroscopyThe Journal of Chemical Physics, 1982
- Spectral bandshape and intensity of the C-H chromophore in the infrared spectra of CF3H and C4F9HChemical Physics Letters, 1980