Systematic characterization and chemical treatment of olive oil mill wastewater

Abstract
Classic and centrifugal olive oil mill wastewater volumes of 1.18 and 1.68m3/Mg olives and corresponding polluting loads of 37 and 53 Kg BOD5 and 82 and 121 Kg COD/Mg olives were established in a systematic study of 15 mills. Lime treatment at an optimum pH level near 11 requiring a dose less than 10g/l effected COD removals from 15 to 22% for classic and from 33 to 46% for centrifugal mill waste. The volume of resulting sludge was large and could not be adequately handled by sedimentation; the sludge had good dewatering characteristics and was amenable to simple straining. Excess lime treatment using up to 50 g/l lime offered little additional benefit.

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