Enantioselective Preparation of a Novel Chiral 1,2-Diamine
- 1 June 2001
- journal article
- research article
- Published by Georg Thieme Verlag KG in Synthesis
- Vol. 2001 (06) , 0863-0866
- https://doi.org/10.1055/s-2001-13406
Abstract
A short enantioselective preparation of (1S,2S)-trans-1,2-diamino-3-cyclohexene using a double [3,3]-sigmatropic rearrangement of an allylic bis(imidate) is described (Overman rearrangement). The starting chiral diol is conveniently obtained by enzymatic resolution.Keywords
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