Magnetism, electronic spectra, and structure of transition metal alkoxides. VI. Chromium(III) chloro alkoxides

1 January 1968

journal article
Published by CSIRO Publishing in Australian Journal of Chemistry

Vol. 21 (6)
https://doi.org/10.1071/ch9681461

Abstract

In the compound Cr(OMe)C12,2CH3OH one molecule of methanol can be replaced by one molecule of acetone, acetonitrile, or dioxan. The magnetism and spectra are interpreted in terms of dimeric models. On heating the dimethanolate one molecule of methanol is lost and for this compound a tetrameric structure is proposed.

Keywords

STRUCTURE
TRANSITION
ACETONITRILE
SPECTRA
COMPOUND
LOST
ALKOXIDES
DIMERIC
REPLACED
DIMETHANOLATE

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