Structure of evaporated cobalt sulphide layers

Abstract
Cobalt sulphide formed by precipitation and also condensed from vapour phase on NaCl or glass substrates at about 200°C had Co3S4 composition with spinel structure. At about 450°C, however, the composition changed to Co9S8 as identified by electron diffraction, and the deposits developed two-degree {100} and {211} orientation with their 〈110〉 axes // 〈110〉 of the rock salt cleavage face.

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