Stereocontrol at ‘off-temple’ sites in 1,2-O-isopropylidene glycofuranoses

1 January 1984

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 16,p. 1122-1123
https://doi.org/10.1039/c39840001122

Abstract

Hydrogenation of the double bond at C(5) of diester (12) occurs exclusively from the si-si face provided that a bulky substituent is present at C(3) in cis relationship to the olefinic side chain.

Keywords

TEMPLE
STEREOCONTROL
BULKY
DOUBLE
GLYCOFURANOSES
DIESTER
ISOPROPYLIDENE
CIS
SUBSTITUENT
SIDE