Synthesis and characterization of η6-Cr(CO)3-indenyl-η3-rhodium-η4-C8H12: an η3:η6co-ordination for the indenyl ligand
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 51-53
- https://doi.org/10.1039/c39890000051
Abstract
Deprotonation of indene–tricarbonylchromium with KH in tetrahydrofuran at –40 °C gives the η6-tricarbonylchromium–indenyl anion which reacts with [Rh(CI)COD]2(COD = cyclo-octa-1,5-diene) to form [η6-Cr(CO)3-indenyl-η3-rhodium-η4- COD]; the same bimetallic complex is obtained by reaction of the rhodium dimer with the isomeric η5-indenyl-tricarbonylchromium anion.Keywords
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