Scenario for the Vogel-Fulcher "law"
- 1 January 1988
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 37 (1) , 676-678
- https://doi.org/10.1103/physrevb.37.676
Abstract
A scenario is presented to explain the Vogel-Fulcher "law" which describes the slowing down of relaxation processes associated with many glasses: . It assumes that relaxation processes are local and satisfy an Arhennius law whose activation energy is determined by the energy needed to jump out of a local potential well. This latter is determined by employing a local Landau expansion of the free energy in powers of the order parameter, where it is assumed that frustration and quenched-in randomness lead to local order which is incompatible with global order. In the free energy, the randomness is considered to provide a linear coupling which drives the quadratic term, with the quartic term preventing the divergence at from actually occurring.
Keywords
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